Search for: All records

Abstract An important role in the cycling of marine trace elements is scavenging, their adsorption and removal from the water column by sinking particles. Boundary scavenging occurs when areas of strong particle flux drive preferential removal of the trace metals at locations of enhanced scavenging. Due to its uniform production and quick burial via scavenging,²³⁰Th is used to assess sedimentary mass fluxes; however, these calculations are potentially biased near regions where net lateral transport of dissolved²³⁰Th violates the assumption that the flux of particulate²³⁰Th to the seabed equals its rate of production in the water column. Here, we present a water column transect of dissolved²³⁰Th along 152° W between Alaska and Tahiti (GEOTRACES GP15), where we examine²³⁰Th profiles across multiple biogeochemical provinces and, novelly, the lateral transport of²³⁰Th to distal East Pacific Rise hydrothermal plumes. We observed a strong relationship between the slope of dissolved²³⁰Th concentration‐depth profiles and suspended particle matter inventory in the upper‐mid water column, reinforcing the view that biogenic particle mass flux sets the background²³⁰Th distribution in open ocean settings. We find that, instead of the region of enhanced particle flux around the equator, hydrothermal plumes act as a regional boundary sink of²³⁰Th. At 152° W, we found that the flux‐to‐production ratio, and thereby error in²³⁰Th‐normalized sediment flux, is between 0.80 and 1.50 for hydrothermal water, but the error is likely larger approaching the East Pacific Rise. 

Worldwide, enhancement of oyster populations is undertaken to achieve a variety of goals including support of food production, local economies, water quality, coastal habitat, biodiversity, and cultural heritage. Although numerous strategies for improving oyster stocks exist, enhancement efforts can be thwarted by longstanding conflict among community groups about which strategies to implement, where efforts should be focused, and how much funding should be allocated to each strategy. The objective of this paper is to compare two engagement approaches that resulted in recommendations for multi-benefit enhancements to oyster populations and the oyster industry in Maryland, U.S.A., using the Consensus Solutions process with collaborative simulation modeling. These recommendations were put forward by the OysterFutures Workgroup in 2018 and the Maryland Oyster Advisory Commission (OAC) in 2021. Notable similarities between the efforts were the basic principles of the Consensus Solutions process: neutral facilitation, a 75% agreement threshold, the presence of management agency leadership at the meetings, a scientific support team that created a management scenario model in collaboration with community group representatives, numerous opportunities for representatives to listen to each other, and a structured consensus building process for idea generation, rating, and approval of management options. To ensure meaningful representation by the most affected user groups, the goal for membership composition was 60% from industry and 40% from advocacy, agency, and academic groups in both processes. Important differences between the processes included the impetus for the process (a research program versus a legislatively-mandated process), the size of the groups, the structure of the meetings, and the clear and pervasive impact of the COVID-19 pandemic on the ability of OAC members to interact. Despite differences and challenges, both groups were able to agree on a package of recommendations, indicating that consensus-based processes with collaborative modeling offer viable paths toward coordinated cross-sector natural resource decisions with scientific basis and community support. In addition, collaborative modeling resulted in ‘myth busting’ findings that allowed participants to reassess and realign their thinking about how the coupled human oyster system would respond to management changes. 

Abstract Three new cestode species are described from the crocodile shark ( Pseudocarcharias kamoharai ) in Ecuador. All three were examined with light and scanning electron microscopy. The unique combination of morphological features in one of the new species prompted formal investigation of the non-monophyly of Paraorygmatobothrium relative to the morphologically similar genera Doliobothrium , Guidus , Marsupiobothrium , Nandocestus , Orectolobicestus , Ruhnkecestus and Scyphophyllidium . Sequence data generated for part of the 28S rDNA gene were subjected to maximum likelihood (ML) analysis. The resulting tree led to the synonymization of six of these seven genera with Scyphophyllidium , and transfer of their species to the latter genus. With the new species, the number of described members of Scyphophyllidium is now 45. The diagnosis of Scyphophyllidium is revised to accommodate these species. In addition, to expedite future descriptions, eight categories of Scyphophyllidium species are circumscribed, based largely on bothridial features. Scyphophyllidium timvickiorum n. sp. is a category 1 species. Beyond being the smallest category 1 species, it bears, rather than lacks, apical suckers and lacks, rather than bears, strobilar scutes. The two other new species are members of Clistobothrium . Clistobothrium amyae n. sp. differs from its congeners in bothridial shape, elongate cephalic peduncle and tiny size. Clistobothrium gabywalterorum n. sp. differs from the two of its congeners that also possess foliose bothridia in overall size and testis number. Despite their substantial morphological differences, the ML tree indicates they are sister taxa. Both are unique among their congeners in possessing cephalic peduncle spinitriches. The diagnosis of Clistobothrium is revised accordingly. 

Abstract The APOGEE Open Cluster Chemical Abundances and Mapping survey is used to probe the chemical evolution of the s-process element cerium in the Galactic disk. Cerium abundances were derived from measurements of Ce ii lines in the APOGEE spectra using the Brussels Automatic Code for Characterizing High Accuracy Spectra in 218 stars belonging to 42 open clusters. Our results indicate that, in general, for ages < 4 Gyr, younger open clusters have higher [Ce/Fe] and [Ce/ α -element] ratios than older clusters. In addition, metallicity segregates open clusters in the [Ce/X]–age plane (where X can be H, Fe, or the α -elements O, Mg, Si, or Ca). These metallicity-dependent relations result in [Ce/Fe] and [Ce/ α ] ratios with ages that are not universal clocks. Radial gradients of [Ce/H] and [Ce/Fe] ratios in open clusters, binned by age, were derived for the first time, with d [Ce/H]/ d R GC being negative, while d [Ce/Fe]/ d R GC is positive. [Ce/H] and [Ce/Fe] gradients are approximately constant over time, with the [Ce/Fe] gradient becoming slightly steeper, changing by ∼+0.009 dex kpc −1 Gyr −1 . Both the [Ce/H] and [Ce/Fe] gradients are shifted to lower values of [Ce/H] and [Ce/Fe] for older open clusters. The chemical pattern of Ce in open clusters across the Galactic disk is discussed within the context of s-process yields from asymptotic giant branch (AGB) stars, gigayear time delays in Ce enrichment of the interstellar medium, and the strong dependence of Ce nucleosynthesis on the metallicity of its AGB stellar sources. 

Abstract Changes in the circulation of the Southern Ocean are known to have impacted global nutrient, heat, and carbon cycles during the glacial and interglacial periods of the late Pleistocene. Proxy‐based records of these changes deserve continued scrutiny as the implications may be important for constraining future change. A record of authigenic uranium from the South Atlantic has been used to infer changes in deep‐sea oxygenation and organic matter export over the past 0.5 million years. Since sedimentary uranium has the possible complication of remobilization, it is prudent to investigate the behavior of other redox‐sensitive trace metals to confidently interpret temporal changes in oxygenation. Focusing here on the exceptionally long interglacial warm period, Marine Isotope Stage (MIS) 11, we found concurrent authigenic enrichments of uranium (U) and rhenium (Re) throughout MIS 12 to 10, overall supporting prior interpretations of low‐oxygen periods. However, there are differential responses of Re and U to oxygen changes and some evidence of small‐scale Re remobilization, which may involve differences in molecular‐level reduction mechanisms. Peaks in authigenic manganese (Mn) intervening with peaks in Re and U indicate increases in porewater oxygenation which likely relate to increased Antarctic Bottom Water circulation at the onset of MIS11c and during the peak warmth of the interglacial around 400 ka.